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The complex 3D Au hexamers were consists of six Au nanospheres linked by thin metal conductive bridges. The conventional deviation associated with the steel conductive bridges and Au nanospheres was within ca. 10%, displaying a high amount of homogeneity and accurate structural tunability. Interestingly, fee transfer among the six Au nanospheres occurred across the steel conductive bridges leading to surface plasmonic coupling between Au nanospheres. Accor