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These results suggest that stable High Five cell pools are a robust and powerful approach to produce VLPs and other recombinant proteins, and put the basis for future studies aiming to scale up this system.Aqueous organic redox flow batteries (AORFBs) are a promising electrochemical technology for large-scale energy storage. We report a biomimetic, ultra-stable AORFB utilizing an amino acid functionalized phenazine (AFP). A series of AFPs with various commercial amino acids at different substituted positions were synthesized and studied.