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Layered transition metal oxides, in particular P2-type ones, are considered as promising cathode materials for sodium-ion batteries on account of their high specific capacity and rate capability. Nevertheless, conventional layered compounds involve detrimental phase transformation throughout repeated cycles, which results in electrochemical performance degradation. Therefore, finding structurally stable layered compounds, featuring minimal phase transition has been a key theme of the sodium-ion battery research. Here lithium substituted