https://allninhibitor.com/any-....peptide-based-gate-i
A comprehensive kinetic analysis indicates the rate deciding step for CO2 decrease could be the reactivity of a Pt hydride intermediate to produce HCO2-. To speed up catalysis, the usage of cationic and hydrogen-bond donor additives are explored.The oxygenation of a benzyl ligand in [PdBnCl(cod)] was significantly accelerated by using secondary phosphine oxides (SPOs), selectively affording either BnOOH or BnOH, according to the focus of O2. The SPOs coordinate to palladium by means of phos