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A series of cyclometalating tridentate N^C^N and tetradentate N^C^N^O ligand-containing complexes of earth-abundant nickel(II) has been designed and synthesized. Among them, the carbazolylnickel(II) complex demonstrates, for the first time, an orange color room-temperature luminescence. Such a complex is also found to exhibit intense luminescence with excited state lifetimes in the submicrosecond regime at 77 K, suggesting the triplet nature of the emissive state. Meanwhile, the self-assembly property of the tetradentate ligand-containi