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Due to the synergistic result, the gel electrolyte exhibits high ionic conductivity (age.g., 14.9 mS cm-1 at -20 °C) and good mechanical properties when compared with nice polyacrylamide solution electrolyte. Benefiting from that, the assembled versatile quasi-solid-state Zn-MnO2 battery exhibits great electrochemical durability and superior threshold to extreme working circumstances. This work provides brand-new views to develop versatile electrochemical energy storage space devices w