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The results of this study provide deep insights into the effects of CeO2 nanocatalyst morphology on the Hg oxidation. Landfill biocovers are an efficient strategy for the mitigation of greenhouse gas emissions from landfills. A complex interplay between key physical and reactive processes occurs in biocovers and affects the transport of gas components. Therefore, numerical models can greatly help the understanding of these systems, their design and optimal operation. In this study, we developed a 3-D multicomponent modeling approach to