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We utilize the super photobase FR0-SB and a series of main, secondary, and tertiary alcohol solvents to illustrate the steric dilemmas associated with solvent to photobase proton transfer. Steady-state and time-resolved fluorescence data show that ESPT occurs easily for major alcohols, with a probability proportional into the relative -OH focus. For additional alcohols, ESPT is considerably diminished, consistent with the barrier levels obtained using quantum chemistry calculati
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