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Three different visible-light photocatalysts (hematite (α-Fe2O3), bismuth vanadate (BiVO4) and Mo-doped bismuth vanadate (BiMoVO4)) deposited on transparent fluorine-doped SnO2 (FTO) were evaluated for the solar-driven photoelectrocatalytic treatment of emerging pollutants. BiMoVO4 was found to be the most effective photoanode, yielding the fastest degradation rate constant and highest mineralization efficiency using phenol as the oxidation probe. The BiMoVO4 photoanode was then used to degrade the herbicide simazine in a photoelectrolyt