https://paksignals.com/index.p....hp/bioavailable-turm
Mechanistic researches reveal that the auxiliary team is vital for C-H activation, and Na2CO3 and an alcoholic solvent play key roles in facilitating the cleavage of this polyfluoroalkylsulfinyl auxiliary.A palladium-catalyzed asymmetric [3+2] cycloaddition reaction of methyleneindolinones with vinylethylene carbonates happens to be effectively developed, which provides a highly efficient way for the formation of structurally diverse 3,3'-tetrahydrofuryl sp
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