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The study of kinetics showed that the volatilization of PbCl2 was controlled by diffusion, and the apparent activation energy is 7.97 kJ/mol. Finally, chlorination roasting residue can be recycled for iron and steel metallurgy.To better deal with the radioactive iodine generated during the development of nuclear energy, B2O3, Bi2O3, ZnO, and SiO2 were used to sinter borosilicate glass for the immobilization of iodine. The effect of B2O3 on glass formation was discussed by changing the molar ratio of B2O3 in the matrix. When B2O3 content