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Phase-change storage and thermal properties of the PCOHs were characterized by differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA), and the PCOHs show high energy transition efficiency and shape stability during the long-term storage and thermal cycling. Dynamic rheology and compression tests demonstrate that PCOHs can withstand a certain stress and display flexibility performance even above the melting temperature of DPDH. We also described the smart temperature management capability and the potential applica