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Trivalent praseodymium exhibits a wide range of luminescent phenomena when doped into a variety of different materials. Herein, radioluminescent NaLuF420%Pr3+ nanoparticles are studied. Four different samples of this composition were prepared ranging from 400-70 nm in size. Kinetic studies of radioluminescence as a function of X-ray irradiation time revealed a decrease in the emissions originating from the 1S0 level, due to the formation or optical activation of defects during excitation, and a simultaneous increase in the visible emissio