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The surface coverage was increased on all the surfaces until a monolayer was obtained. The highest surface coverage for S shows the trend (001)S = (111)S (011)S, and for SO it is (001)SO (011)SO (111)SO, similar to SO3 where we found (001)SO3 (011)SO3 (111)SO3. These trends indicate that the (001) surface is more susceptible to S species poisoning. It is also evident that both the (001) and (111) surfaces were reactive toward S, leading to the formation of S2. The high coverage of SO3 showed the formation of SO2 and SO4, especially