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Energy shortage and wasting of resources are two main challenges for human society. To solve these problems, nitrogen-doped porous carbon was synthesized through a simple thermally induced phase separation (TIPS) method with subsequent carbonization and activation with biomass konjac/polyacrylonitrile composites as the raw materials and nitrogen source for the first time. The obtained composite carbon with hierarchical porosity, large specific surface areas, and high content of nitrogen doping shows promise due to its desirable electroch