https://www.selleckchem.com/pr....oducts/epertinib-hyd
The coordination characteristics and donor/acceptor properties of a series of 2-pyridyl substituted phosphine ligands have been investigated using structural, spectroscopic and DFT calculational studies. A range of different coordination modes are observed in Mo and W carbonyl complexes of tris-2-pyridyl-phosphine ligands of the type P(2-py' (2-py' = substituted or unsubstituted 2-pyridyl group), including an unprecedented example exhibiting N,N',μ2-π coordination. DFT calculations were used to assess the relative donor