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Although commonly implemented, little is known about their fundamental chemistry, which can be a crucial space for development of brand new fuel materials and radioactive waste management techniques. Utilising a genuine method, we straight evidence the biochemistry of Cr(3+)2O3-doped U(4+)O2. Advanced high-flux, high-spectral purity X-ray absorption spectroscopy (XAS), corroborated by diffraction, Raman spectroscopy and high energy s