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Metal-based aqueous redox flow batteries (ARFBs) such as zinc-based ARFBs have attracted remarkable attention owing to their intrinsic high energy density. However, severe dendrite issues limit their efficiency and lifespan. Here an aqueous metal anode operating between Sn(OH)62- (stannate) and metal Sn is presented, providing a reversible four-electron transfer at -0.921 V vs standard hydrogen electrode. In strong contrast to severe Zn dendrites, the Sn(OH)62- /Sn electrode shows smooth and dendrite-free morphology, which can be attrib
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