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A total of 100 compounds in Huangdi Anxiao Capsules had been identified, including 25 compounds from Pueraria Lobate Radix, 22 substances from Coptis Rhizoma, 6 compounds from Ophiopogonis Radix, 14 compounds from Eriobotryae Folium, 22 substances from Rehmanniae Radix, and 15 substances from Notoginseng Radix et Rhizoma. Among them, 3 substances were typical elements. These 100 substances included flavonoids, alkaloids, saponins and organic acids. This study system