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In this study, competitive adsorption behaviour and mechanisms of Cd2+, Ni2+ and NH4+ by fresh and artificially ageing biochars produced from rice straw at 400 and 700 °C (RB400, RB700, HRB400 and HRB70 were investigated. Cd2+ competed with Ni2+ and NH4+ for the overlapped adsorption sites on the biochars. For Cd2+ and Ni2+ adsorption, cation exchange (Qci) and mineral co-precipitation (Qcp) were the primary mechanisms for the low-temperature and high-temperature biochars, respectively. However, the other potential mechanisms (Qco) ma