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A new hybrid system is proposed to capture CO2 as well as generate electricity with the low CO2 inlet condition of confined space. Within the system, a novel photocatalytic porous framework coated by g-C3N4/TiO2 is prepared to avoid the inhibition of microalgae growth caused by the direct addition of photocatalyst. Under 0.8% v/v CO2 inlet condition, chemical oxygen demand (COD) yields from the photocatalytic framework immersed in the phosphate buffer and the algae suspension are 1.63 mg L-1 h-1 and 1.90 mg L-1 h-1, respectively. CO2 s