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The limit of recognition (LoD) of Fe3+ ions within the long-range of 16-363 µM for the basic and protonated forms of 7AI is 0.46 ± 0.02 and 0.49 ± 0.02 µM, correspondingly, calculated using FL spectra. Additionally, the linear plot of absorbance with Fe3+ ions of both the forms of 7AI also can act as a calibration bend with really close LoDs, as gotten by FL spectra. Hence, the multi-parameters-based probe for detecting the Fe3+ ions over long-range in real aqueous con