https://www.selleckchem.com/pr....oducts/opb-171775.ht
This Article analyzes the thermodynamic principles of ST reactions and demonstrates that the unidirectional nonenzymatic reaction can be run without thermodynamic favorability by transforming thermodynamically stable substrates into metastable products. In other words, ST is capable to drive nanomachines using thermodynamically uphill reactions. This allows for (i) running nanodevices without detrimental background activity and (ii) charging the product molecules with potential energy, which could be used in downstream endergonic act
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