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A phenomenological model is exploited to obtain the thermomagnetic parameters. The magnon drag and phonon drag largely decide the thermoelectric power in the low-temperature ferromagnetic region, whereas the small polaron hopping of carriers contributes to the TEP in the high-temperature paramagnetic region. A colossal TEP value of -800 μV K-1 is observed at around 14 K for the x = 0.3 sample.A trimeric tri-Tb3+-including antimonotungstate (AMT) hybrid Na17(WO4)[Tb(H2O)(Ac)(B-α-SbW9O31(OH)2)]3·50H2O (Tb3W28) was successfully synthesized,