https://www.selleckchem.com/pr....oducts/gsk2193874.ht
Electrochemical investigations showed that the reduced state of manganese(iii) centers in 3 is easily accessible in comparison to complexes 1 and 2.Five pairs of novel chiral alcohol functionalised gold(i) and gold(iii) NHC complexes derived from chiral amino alcohols, were synthesized and characterised (NMR, IR, HRMS). Single crystal X-ray diffraction data of gold(i) and gold(iii) complexes are reported and discussed. The chiral imidazolium preligands were readily synthesized via the oxalamides, subsequent reduction and final orthof
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